I'm all for it and I'd vote for him. There's even a blogger cabinet being assembled over at Smallest Minority. Some of my favorite nominations:
VP: Rachel Lucas - With her guns, you can bet she won't be hiding out at some "undisclosed location".
Attorney General: Eugene Volokh - I can't quite put my finger on why, but he just seems like an excellent choice.
Defense WAR!: Donald Sensing - Retired
Army artillery officer and ordained minister. I agree that this combination is a plus.
Sec. of State: Steven Den Beste - This choice is borderline genius. Also nominated for Head of the CIA/NSA, he would serve well in either position.
Sec. of Treasury: Mindles H. Dreck - Not bad, but I wonder if Mindles wouldn't serve better as Chairman of the Federal Reserve Board.